Four-Coordinate Iron(II) Porphyrinates: Electronic Configuration Change by Intermolecular Interaction
نویسندگان
چکیده
منابع مشابه
Proton-mediated electron configuration change in high-spin iron(II) porphyrinates.
The synthesis, molecular structure, and electronic structure characterization of two five-coordinate high-spin imidazolate-ligated iron(II) porphyrinates are reported. Their electronic structure, as deduced from Mössbauer spectra obtained in strong magnetic fields, is distinctly different from that of the analogous imidazole-ligated species. The resulting electronic structure models are consist...
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2007
ISSN: 0020-1669,1520-510X
DOI: 10.1021/ic0620182